If we stack a rectangle on top of itself we have a rectangle twice the height. The additivity principle says that the area of the so-formed rectangle is the sum of the areas of the stacked rectangles. Our definition of integral for simple functions has this property.
In this notation, we want to show that $s(\alpha f) = \alpha s(f)$ for all $\alpha \in [0, \infty)$ and $f \in \SimpleF_+(X)$. Toward this end, let $f \in \SimpleF_+(X)$ with the simple partition $\set{A_n} \subset \mathcal{A} $ and $\set{a_n} \subset [0, \infty]$.
First, let
$\alpha \in (0, \infty)$.
Then $\alpha f \in \SimpleF_+(X)$,
with the simple partition
$\set{A_n} \subset \mathcal{A} $
and $\set{\alpha a_n} \subset [0, \infty]$.
\[
s(\alpha f) = \sum_{i = 1}^{n} \alpha a_n \mu (A_i)
= \alpha \sum_{i = 1}^{n} a_n \mu (A_i)
= \alpha s(f).
\]