Since we have a partial order on the set of positive semidefinite matrices, we can study which familiar functions are have order-preserving or order-reversing properties.
It would be nice if the matrix norm induced by the matrix scalar produce (see Matrix Scalar Product) was an isotonic function. In other words, if $A, B \in \mathbfsf{S} ^d$ satisfy $A \geq B$, does $\norm{A} \geq \norm{B}$?
Since $\norm{A}^2 = \tr A^2$, we should study the trace first..
In other words, the function $f$ is the restriction of the trace function onto the set of symmetric matrices.